Source
Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, 2022, p. 127
Publisher
Belgrade : Serbian Chemical Society
Authors
Handle
https://hdl.handle.net/21.15107/rcub_cer_5081
Poster
https://hdl.handle.net/21.15107/rcub_cer_5085
Categories
Keywords
Publishing date

Abstract

The HLCl ligand with metal salts Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O and NaN3, in methanol form mononuclear penta-coordinated complexes [CuL(N3)(CH3OH)]BF4 (1) and [ZnL(N3)2] (2) and binuclear [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3) complex. Complexes 1, 2 and 3 were characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, and DFT calculations.